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31.
The tape stripping technique is an experimental method frequently used for reconstruction of the in-depth distribution of various topically administered substances within the horny layer of human skin, e.g., compounds contained in sunscreens. Titanium dioxide (TiO2) nanoparticles (25–200 nm in diameter) are one such compound. Optical techniques which apply blue light are found to be suitable for reconstruction. However, the presence of particles affects the light propagation within the skin and therefore causes incorrect determination of strip thickness, leading to an improper reconstructed distribution of nanoparticle concentration revealed from the experimental data. This study evaluates the errors emerging from the use of blue (400 nm) and NIR (800 nm) radiation and finds the use of longer wavelength light more advantageous. Particles of different diameters are considered, and it is revealed that the application of small particles (25–60 nm) results in the lowest rate of error. 相似文献
32.
A Volterra type integral equation in a Hilbert space with an additional linear operator L and a spectral parameter depending
on time is considered. If the parameter does not belong to the spectrum of L unconditional solvability of the considered problem
is proved. In the case where the initial value of the parameter coincides with some isolated point of the spectrum of the
operator L sufficient conditions for solvability are established. The obtained results are applied to the partial integral
equations associated with a contact problem of the theory of elasticity. 相似文献
33.
Generalized Noether theorems and applications 总被引:3,自引:0,他引:3
We generalize the first and second Noether theorems (Noether identities) to a constrained system in phase space. As an example, the conservation law deriving from Lagrange's formalism cannot be obtained fromH
E
via the generalized first Noether theorem (GFNT); Dirac's conjecture regarding secondary first-class constraints (SFCC) is invalid in this example. A preliminary application of the generalized Noether identities (GNI) to nonrelativistic charged particles in an electromagnetic field shows that on the constrained hypersurface in phase space one obtains electric charge conservation. This conservation law is valid whether Dirac's conjecture holds true or not. 相似文献
34.
It is proved that biorthogonal polynomials obey two different kinds of Christoffel-Darboux-type formulae, one linking polynomials with a different parameter and one combining polynomials with different degrees. This is used to produce a mixed recurrence relation, which is valid for all biorthogonal polynomials. This recurrence relation establishes several results on interlacing property of zeros of successive biorthogonal polynomials and leads to a new result on the interlace of zeros of orthogonal polynomials (of equal degrees) with respect to two distributionsdψ(x) andx p dψ(x), 0<p≤1, with support in either [0, 1] or [1, ∞). 相似文献
35.
36.
Guofen Yu Yuanci Gao Shenggang Liu Wenxiang Wang Jin Wu 《International Journal of Infrared and Millimeter Waves》2002,23(8):1261-1269
Analysis of the field distributions in a single biological cell under electromagnetic wave is given. With Debye approximation, the dielectric relaxation of each part of the cell, including the extracellular and cellular media, the cell membrane and the nuclear membrane, was taken into account. Making use of some typical parameters for a cell, the voltage across nuclear and cytoplasma membranes under electromagnetic waves are calculated up to millimeter wave frequency range. The calculated result indicates that it is unlikely to generate electroporation by present available millimeter wave sources. 相似文献
37.
38.
应用密度泛函理论,本文系统地研究了O在Au(111)表面上的吸附能、吸附结构、功函数、电子密度和投影态密度,给出了覆盖度从0.11ML到1.0ML的范围内,O的吸附特性随覆盖度变化的规律.研究发现O的稳定吸附位为3重面心立方(fcc)洞位,O在fcc洞位的吸附能对覆盖度比较敏感,其值随着覆盖度的增加而减小;O诱导Au(111)表面功函数的变化量与覆盖度成近线性关系,原因是Au表面电子向O偏移,形成表面偶极子;O—Au的相互作用形成成键态和反键态,且反键态都被占据,造成O—Au键很弱,O吸附能较小.
关键词:
表面吸附
Au(111)表面
密度泛函理论
电子特性 相似文献
39.
40.
The high-temperature cubic phase of non-stoichiometric strontium ferrite SrFeOx (2.5≤x≤3.0) has been studied by in situ neutron powder diffraction in air over the temperature range 300-1273 K. The composition of SrFeOx changes within the range 2.56≤x≤2.81 from 1273 to 673 K, respectively.Rietveld refinements of the diffraction patterns show that the high-temperature cubic phase of SrFeOx is consistent with a face-centred Fm3c structure. This structure leads to agreement with previous density measurements. This cell allows the high-temperature structure of SrFeOx to be described in terms of a solid solution of the composition end members. Cubic SrFeOx at high temperature is found to closely obey Vegard's law. The density of cubic SrFeOx is also found to exhibit a linear relationship with composition. 相似文献